The Copa Libertadores final between Flamengo and River Plate will be shown live on BBC Two, BBC iPlayer, the BBC Sport website and the BBC Sport app on Saturday, 23 November from 19:45 GMT.
Defending champions River Plate overcame fellow Argentines and fierce rivals Boca Juniors in the last four.
Brazil's Flamengo have two of the tournament's top scorers in Gabriel Barbosa (seven) and Bruno Henrique.
South America's top club competition began with 47 teams in January.
The winner of the 60th Copa Libertadores final, held at The Estadio Monumental in Lima, Peru, will qualify for the 2019 Fifa Club World Cup, alongside Champions League winners Liverpool, in Qatar.