Great Britain suffered a 2-1 defeat against Germany and missed out on the semi-finals of the London Cup, their final pre-Olympic tournament.
The visitors scored twice in quick succession, through Hannah Kruger and Janine Beermann, to leave Britain 2-0 behind at the break.
Hannah Macleod's goal with 11 minutes remaining gave the home side hope but they missed excellent late chances.
Britain will meet Ireland in the fifth-sixth play-off on Sunday.
View the Olympic schedule
Visit the London 2012 official website to find out which teams are playing in which session.
Great Britain, who won the recent
Olympic test event by defeating Argentina in the final,
had needed to win by two goals to make the last four.
Saturday's semi-finals see Australia take on Germany and the Netherlands face South Africa.