Miracle material graphene can distil booze, says study

Graphene Graphene and its derivatives display many unusual and useful properties

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Membranes based on the "miracle material" graphene can be used to distil alcohol, according to a new study in Science journal.

An international team created the membrane from graphene oxide - a chemical derivative of graphene.

They have shown that the membrane blocks the passage of several gases and liquids, but lets water through.

This joins a long list of fascinating and unusual properties associated with graphene and its derivatives.

Graphene is a form of carbon. It is a flat layer of carbon atoms tightly packed into a two-dimensional honeycomb arrangement.

Because it is so thin, it is also practically transparent. As a conductor of electricity, it performs as well as copper; and as a conductor of heat, it outperforms all other known materials.

The unusual electronic, mechanical and chemical properties of graphene at the molecular scale promise numerous applications.

Graphene

  • Graphene is a form of carbon that exists as a sheet, one atom thick
  • Atoms are arranged into a two-dimensional honeycomb structure
  • Identification of graphene announced in October 2004
  • About 100 times stronger than steel and conducts electricity better than copper
  • About 1% of graphene mixed into plastics could turn them into electrical conductors
  • Analogous to millions of unrolled nanotubes stuck together

Andrei Geim and Konstantin Novoselov from the University of Manchester were awarded 2010's Nobel Prize in physics for their discovery, outlined in a scientific paper in 2004.

Geim and others have now developed a laminate made from thin sheets of graphene oxide.

These films were hundreds of times thinner than a human hair but remained strong, flexible and easy to handle.

When a metal container was sealed with such a film, even the most sensitive equipment was unable to detect air or any other gas, including helium, leaking through.

But when the researchers tried the same with water, they found that it evaporated without noticing the graphene seal. Water molecules diffused through the graphene-oxide membranes with such a great speed that the evaporation rate was the same whether the container was sealed or open.

'Just for a laugh'

Dr Rahul Nair from Manchester University, who led the team, commented: "Graphene oxide sheets arrange in such a way that between them there is room for exactly one layer of water molecules.

He added: "If another atom or molecule tries the same trick, it finds that graphene capillaries either shrink in low humidity or get clogged with water molecules."

Professor Geim added: "Helium gas is hard to stop. It slowly leaks even through a millimetre-thick window glass but our ultra-thin films completely block it. At the same time, water evaporates through them unimpeded. Materials cannot behave any stranger."

Dr Nair said: "Just for a laugh, we sealed a bottle of vodka with our membranes and found that the distilled solution became stronger and stronger with time. Neither of us drinks vodka but it was great fun to do the experiment."

Despite this, the researchers do not offer any immediate ideas for applications. But Professor Geim commented: "The properties are so unusual that it is hard to imagine that they cannot find some use in the design of filtration, separation or barrier membranes, and for selective removal of water."

In another study in Science journal, a different team reports the development of a membrane based on diamond-like carbon. This membrane has unique pore sizes that allow for the ultra-fast passage of oil through it.

One expert said it could potentially be used for filtering toxic contaminants out of water or for purifying industrial chemicals.

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